vialroom
Thread · #hplc-massspec · 2025-07-28

a warm transit can put a visible degradant peak

Spun off from a message in #hplc-massspec on 2025-07-28. 11 messages, 4 participants.

The message this came from
  • vial_ledger — a warm transit can put a visible degradant peak on a chromatogram. that is what 24 days at ambient does 15:13
TT

214nm sees the amide backbone so it sees everything. 280 only sees aromatics

VL

if the lab reports area percent without stating the wavelength, the number is less useful than it looks

VL

if somebody says they ran a mass spec and does not show you a spectrum, that is a claim, not a result

need more sample

VL

a certificate with a number and no chromatogram is asking you to trust the integration you cannot see

HH

ms/ms sequencing is the only thing i would call identity. everything else is circumstantial